Nonlinear optical crystal LB4 (Li2B4O7)

LiB4O7

(lithium tetraborate)

100 0007

Main Properties

Transparency range, µm 0.16 – 3.5
Nonlinear coefficient, pm/V d31 = 2.0; d31 = 0.12
Symmetry Tetragonal, 4mm point group
Cell parameters, Å a=12.818, b=6.404, c=10.596
Typical
Reflection
index

1064 nm
532 nm

no=1.5980, ne=1.5432
no=1.6139, ne=0.5564
Optical
Damage
Threshold, GW/cm2

1064 nm
(t=10 ns)
1
Walk off angle, ° (532 nm) 1.9
Mohs hardness 4-5
Chemical properties Non-hygroscopic

The parameters of optical elements

Orientation accuracy, arc min < 30
Parallelism, arc sec < 30
Flatness 546 nm λ/6
Surface quality, scratch/dig 20/10

Application

  • Substrate for a surface acoustic wave (SAW) devices
  • Harmonics generation (SHG, THG, 4HG, 5HG) of YAG lasers
  • High power ultraviolet light source based on SHG and SFG of the visible radiation.